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Free radicals of isatoic anhydride and its derivatives as studied by in situ electrochemical-ESR-technique

 
Ber. Bunsenges. Phys. Chem. 98 (1994), 1033-1038
A. Petr, L. Dunsch, A. Neudeck, N. Oesterreich, M. Mann, G. Domschke


 
Abstract
The electrochemical reduction of isatoic anhydride and its derivatives was studied by simultaneous electrochemical and ESR-measurements. For the first time 9 new radicals were characterized by its formal redox potentials, hyperfine coupling constants, g-factors and lifetimes. The advantage of measuring the kinetic data in stagnant and renewed electrolyte combined with accumulation of the ESR-spectra is demonstrated in the case of shortlived radicals. It is shown that the electrochemical reduction of isatoic structures follows a self protonation mechanism.

 
 

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